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Author Sereni, J.G.; Nieva, G.; Kappler, J.P.
Title (up) ANOMALOUS CRYSTAL-FIELD EFFECTS IN THE SPECIFIC-HEAT OF CE-HEAVY FERMION COMPOUNDS Type Journal Article
Year 1987 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 63-64 Issue Pages 101-103
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ISSN 0304-8853 ISBN Medium
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Notes ISI:A1987G356900031 Approved no
Call Number BT @ hernan @ Serial 128
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Author KAPPLER, J.P.; SCHMERBER, G.; SERENI, J.G.
Title (up) CERIUM MAGNETIC-BEHAVIOR IN CE(PD,M) WITH M = CO, NI, RH, IR, PT, CU, AG AND AU Type Journal Article
Year 1988 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 76-7 Issue Pages 185-186
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Notes ISI:A1988T046300057 Approved no
Call Number BT @ hernan @ Serial 124
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Author Sereni, J.G.; Trovarelli, O.; Schmerber, G.; Kappler, J.P.
Title (up) Coexistence of magnetic order and heavy fermion behavior in Ce7X3 Type Journal Article
Year 1992 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 108 Issue 1-3 Pages 183-184
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Abstract Low temperature specific heat and magnetic susceptibility measurements on Ce7X3 (X = Rh, Ni) compounds are reported. Ce7Rh3 shows an onset of spontaneous magnetization at 7.2 K. About 40% of the expected R ln 2 entropy gain is found in the paramagnetic phase, related to a gamma(HT) = 1.1 J/K2 mol specific heat coefficient. In Ce7Ni3 an antiferromagnetic transition is observed at 1.7 K, superimposed to a large C(p)/T electronic contribution, described by a gamma(HT) = 0.9 J/K2 mol coefficient for T > 10 K. These results are interpreted in terms of the three different crystal sublattices of Ce. The entropy gain related to each transition allows to identify the behaviour of each sublattice. In the case of Ce7Ni3 one sublattice behaves as a heavy fermion system, with a value of C(p)/T = 3.3 J/K2 Ce at. Such a behaviour is confirmed under an applied magnetic field.
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Notes ISI:A1992HH32900075 Approved no
Call Number BT @ hernan @ Serial 113
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Author Sereni, J.G.; Nieva, G.; Huber, J.G.; Braun, E.; Oster, F.; Bruck, E.; Roden, B.; Wohlleben, D.
Title (up) Evidence for 4f-instability of dilute terbium in thorium Type Journal Article
Year 1987 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 63-64 Issue Pages 597-599
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Abstract We have measured the specific heat of dilute Th1?xTbx alloys (0.44 < x < 2.15 a/o), which rises linearly between 0.4 and 0.9 K with a slope of ?C/T ? 450 mJ/K2molTb followed by a Schottky anomaly with a maximum near 3.8 K. The high temperature ??T product was found to be 4% lower than that of Tb3+. The resistivity shows no minimum at low temperatures. Discussion is made in terms of non-integral valence of Tb.
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Notes ISI:A1987G356900173 Approved no
Call Number BT @ hernan @ Serial 129
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Author Facio, J.I.; Betancourth, D.; Cejas Bolecek, N.R.; Jorge, G.A.; Pedrazzini, P.; Correa, V.F.; Cornaglia, P.S.; Vildosola, V.; García D.J.
Title (up) Lattice specific heat for the RMIn5 (R=Gd, La,Y; M=Co, Rh) compounds: Non-magnetic contribution subtraction Type Journal Article
Year 2016 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 407 Issue Pages 406-4011
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Call Number BT @ victor.correa @ Serial 730
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Author Betancourth, D.; Facio, J.I.; Pedrazzini, P.; Jesus, C.B.R.; Pagliuso, P.G.; Vildosola, V.; Cornaglia, P.S.; García, D. J.; Correa, V. F.
Title (up) Low Temperature magnetic properties of GdCoIn5 Type Journal Article
Year 2015 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 374 Issue Pages 744-747
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Abstract A comprehensive experimental and theoretical study of the low temperature properties of GdCoIn5 was performed. Specific heat, thermal expansion, magnetization and electrical resistivity were measured in good quality single crystals down to 4He temperatures. All the experiments show a second-order-like phase transition at 30 K probably associated with the onset of antiferromagnetic order. The magnetic susceptibility shows a pronounced anisotropy below T N with an easy magnetic axis perpendicular to the crystallographic ĉ-axis. Total energy GGA+U calculations indicate a ground state with magnetic moments localized at the Gd ions and allowed a determination of the Gd-Gd magnetic interactions. Band structure calculations of the electron and phonon contributions to the specific heat together with Quantum Monte Carlo calculations of the magnetic contributions show a very good agreement with the experimental data. Comparison between experiment and calculations suggests a significant anharmonic contribution to the specific heat at high temperature (View the MathML sourceT≳100K).
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Call Number BT @ victor.correa @ Serial 701
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Author Braghta, A.; Schmerber, G.; Derory, A.; Sereni, J.G.; Kappler, J.P.
Title (up) Magnetic and thermal properties of Ce2Pd2Sn Type Journal Article
Year 2008 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 320 Issue 6 Pages 1141-1145
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Abstract X-ray diffraction, susceptibility and specific heat studies on ternary Ce2Pd2Sn intermetallic compound and on its isostructural nonmagnetic compound La2Pd2Sn are reported. On Ce2Pd2Sn in absence of magnetic field, we confirm the existence of two magnetic transitions at T-N = 4.8K (antiferromagnetic transition) and T-C = 2.2K (ferromagnetic transition) and the specific heat results, measured down to 0.5 K, allow to recognize the transition at 2.2K as a first-order transition. A description based on molecular field calculations for the S = 1/2 resonant level model leads to a characteristic Kondo T-K of about 3K. (C) 2007 Elsevier B.V. All rights reserved.
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Notes ISI:000254416300060 Approved no
Call Number BT @ hernan @ Serial 49
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Author Kappler, J.P.; Schmerber, G.; Sereni, J.G.
Title (up) Magnetic and thermal properties of Ce5Rh3 Type Journal Article
Year 1992 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 115 Issue 2-3 Pages 241-244
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Abstract Magnetic susceptibility, high field magnetization and specific heat measurements on Ce5Rh3 are reported. Two antiferromagnetic transitions are observed at T(N)=4.5 K and T(N)'=2.6 K. The magnetization curve at 1.5 K reveals a nontrivial magnetic structure in this compound, with a saturation magnetization of 0.72mu(B). The high temperature Curie constant (0.64 emu K/mol), the Curie-Weiss constant (THETA(p)=-45 K) and the entropy related with the magnetic transitions (DELTAS(m)=0.8 R In 2) indicate the presence of a Kondo-type component in the ground state of Ce5Rh3.
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Notes ISI:A1992JV02200022 Approved no
Call Number BT @ hernan @ Serial 111
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Author Sereni, J.G.; Kappler, J.P.
Title (up) Magnetic and thermal properties of CeCu Type Journal Article
Year 1992 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 109 Issue 2-3 Pages 349-352
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Abstract Magnetic susceptibility, high field magnetization and specific heat measurements on CeCu are presented. An antiferromagnetic transition is observed at T(N) = 313 K, with some evidences of low dimensionality of the order parameter. The saturation magnetization. M(s) = 1.16-mu(B), implies that the crystalline electric field (CEF) ground state doublet is strongly magnetic, in agreement with the low temperature Curie constant C = 0.46 emu K/mol. In the high temperature limit (T > 50 K), the obtained Curie constant is C = 0.65 emu K/mol, which suggests an overall CEF splitting larger than 200 K. The entropy gain at the magnetic transition is 72% of the expected R in 2. The missing entropy is related to a specific heat anomaly with a maximum at approximately 13 K, which is attributed to magnetic fluctuations in the Ce chains. The transition temperature and the high temperature broad maximum in the specific heat are weakly affected by an applied magnetic field of 1 T.
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Notes ISI:A1992HP06000034 Approved no
Call Number BT @ hernan @ Serial 112
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Author Vildosola, V.L.; Llois, A.M.; Weissmann, M.; Sereni, J.G.
Title (up) Magnetic behaviour of Ce(Pd1-xMx) compounds (M = Rh, Ni and Ag) within the LDA approximation Type Journal Article
Year 2001 Publication Journal of Magnetism and Magnetic Materials Abbreviated Journal J. Magn. Magn. Mater.
Volume 236 Issue 1-2 Pages 6-8
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Abstract Ce intermetallic compounds have been intensively studied in the last few decades due to the large variety of behaviours they exhibit. In particular, two ways of demagnetizing Ce have been experimentally tried within the ferromagnetic systems Ce(Pd1-xMx), namely through electronic concentration variations (M=Rh) and volume reductions (M=Ni). On the other hand, when Pd is substituted by Ag, a transformation from a ferromagnetic to an antiferromagnetic ground state has been observed. In this work, we analyse the evolution of the magnetism of Ce in the above-mentioned family of compounds by calculating the spin contribution to magnetism that results from spin polarised LDA calculations. (C) 2001 Elsevier Science B.V. All rights reserved.
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Notes ISI:000171670100004 Approved no
Call Number BT @ hernan @ Serial 75
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