Abstract: We report the fabrication of high-Tc superconducting wires by photodoping a GdBa2Cu3O6.5 thin film. An optical near-field probe was used to locally excite carriers in the system at room temperature. Trapping of the photogenerated electrons define a confining potential for the conducting holes in the CuO planes. Spatially resolved reflectance measurements show the photogenerated nanowires to be ?250 nm wide. Electron diffusion, before electron capture, is believed to be responsible for the observed width of the wires.

Abstract: We present an exhaustive analysis of transport measurements performed in twinned YBa2Cu3O7 single crystals which establishes that the vortex solid-liquid transition is first order when the magnetic field H is applied at an angle ? away from the direction of the twin planes. We show that the resistive transitions are hysteretic and the V-I curves are nonlinear, displaying a characteristic S shape at the melting line Hm(T), which scales as ?(?)Hm(T,?), where ?(?) is the anisotropy factor. These features are gradually lost when the critical point H*(?) is approached. Above H*(?) the V-I characteristics show a linear response in the experimentally accessible V-I window, and the transition becomes reversible. Finally we show that the first-order phase transition takes place between a highly correlated vortex liquid in the field direction and a solid state of unknown symmetry. As a consequence, our data support the scenario for a vortex-line melting in twinned YBa2Cu3O7 crystals in contrast to a vortex sublimation as recently suggested for untwinned La2-xSrxCuO4, YBa2Cu3O7 and Bi2Sr2CaCu2O8 [T. Sasagawa et al., Phys. Rev. Lett. 80, 4297 (1998)].

Abstract: Raman scattering in detwinned YBa2Cu3O6.65 single crystals is studied as a function of photoexcitation and annealing. Copper-oxygen chain-related forbidden Raman bands that are known to strongly bleach with illumination at low temperatures, increase their intensity with chain fragmentation induced by annealing at high temperature. This contrasting behavior proves the conjunction of short Cu-O fragments into longer chains on photoexcitation. We interpret the Raman modes as due to vibrations at the end of CuO chain fragments and Cu-O-Cu monomers, and use their evolution with illumination and annealing as anisotropic sensitive markers of oxygen reordering processes. The identification of the “forbidden” Raman bands is discussed in the context of our results and recent literature in the subject. We also present absorption measurements performed on GdBa2Cu3Ox thin films with varying oxygen content. These experiments show that the 2.2-eV absorption and the chain-related Raman peaks have different dependencies with oxygen content and illumination, ruling out an explanation that suggests that the Raman intensity reduction of these modes is due to a photobleaching of intermediate defect states. These results highlight the potentialities of Raman scattering for oxygen dynamics studies and demonstrate the presence of photoinduced oxygen ordering in these high-Tc superconductor compounds.

Abstract: We present the evolution of magnetic and structural properties of Y1-xPrxBa2Cu3Oy (xsimilar to0.5 and x = 1) single crystals and polycrystalline materials when the oxygen concentration y is varied from under- to overdoping. We have found a monotonous evolution of the Pr Neel temperature for x = 1 samples and a maximum of the superconducting critical temperature for the xsimilar to0.5 samples. The structural properties as detected by X-ray diffraction and Raman spectroscopy show no instabilities when crossing the optimal doping region as was found in the x = 0 material. (C) 2002 Elsevier Science B.V. All rights reserved.