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Lora-Serrano, R., V. F. Correa, C. Adriano, C. Giles, J. G. S. Duque, E. Granado, P. G. Pagliuso, T. P. Murphy, E. C. Palm, S. W. Tozer et al. "First order magnetic transition and magnetoelastic effects in Sm2IrIn8." Physica B 403, no. 5-9 (2008): 1365–1367.
Abstract: We report measurements of temperature dependent heat capacity, thermal expansion and high resolution X-ray diffraction (XRD) taken on single crystals of Sm2IrIn8 intermetallic compound. This compound belongs to the RmMnIn3m+2n family (R=rare earth, m=1, 2, n=0, 1 and M=Rh, Ir and Co) which includes a number of heavy fermion superconductors for R=Ce. Particularly, Sm2IrIn8 is the only member of this family to present a first order magnetic phase transition (FOMT). Both thermal expansion and heat capacity data show very pronounced sharps peaks at View the MathML source consistent with an FOMT. The linear thermal-expansion coefficient is anisotropic and both c-axis and basal ab plane coefficients change discontinuously at 14.2 K. This change is negative for both direction in contrast to what was found for other members of family such as Ce2RhIn8 and CeRhIn5. The zero-field high resolution XRD data at 14.2 K shows no evidence for a tetragonal-to-orthorhombic structural phase transition. We discuss our results considering tetragonal crystalline field effects (CEF), quadupolar interactions, antiferromagnetic domains and magnetoelastic effects.
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Betancourth, D., J. I. Facio, P. Pedrazzini, C. B. R. Jesus, P. G. Pagliuso, V. Vildosola, P. S. Cornaglia, D. J. García, and V. F. Correa. "Low Temperature magnetic properties of GdCoIn5." Journal of Magnetism and Magnetic Materials 374 (2015): 744–747.
Abstract: A comprehensive experimental and theoretical study of the low temperature properties of GdCoIn5 was performed. Specific heat, thermal expansion, magnetization and electrical resistivity were measured in good quality single crystals down to 4He temperatures. All the experiments show a second-order-like phase transition at 30 K probably associated with the onset of antiferromagnetic order. The magnetic susceptibility shows a pronounced anisotropy below T N with an easy magnetic axis perpendicular to the crystallographic ĉ-axis. Total energy GGA+U calculations indicate a ground state with magnetic moments localized at the Gd ions and allowed a determination of the Gd-Gd magnetic interactions. Band structure calculations of the electron and phonon contributions to the specific heat together with Quantum Monte Carlo calculations of the magnetic contributions show a very good agreement with the experimental data. Comparison between experiment and calculations suggests a significant anharmonic contribution to the specific heat at high temperature (View the MathML sourceT≳100K).
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