Abstract: Raman scattering in detwinned YBa2Cu3O6.65 single crystals is studied as a function of photoexcitation and annealing. Copper-oxygen chain-related forbidden Raman bands that are known to strongly bleach with illumination at low temperatures, increase their intensity with chain fragmentation induced by annealing at high temperature. This contrasting behavior proves the conjunction of short Cu-O fragments into longer chains on photoexcitation. We interpret the Raman modes as due to vibrations at the end of CuO chain fragments and Cu-O-Cu monomers, and use their evolution with illumination and annealing as anisotropic sensitive markers of oxygen reordering processes. The identification of the “forbidden” Raman bands is discussed in the context of our results and recent literature in the subject. We also present absorption measurements performed on GdBa2Cu3Ox thin films with varying oxygen content. These experiments show that the 2.2-eV absorption and the chain-related Raman peaks have different dependencies with oxygen content and illumination, ruling out an explanation that suggests that the Raman intensity reduction of these modes is due to a photobleaching of intermediate defect states. These results highlight the potentialities of Raman scattering for oxygen dynamics studies and demonstrate the presence of photoinduced oxygen ordering in these high-Tc superconductor compounds.

Abstract: We study the dependence of the transport properties of square Josephson Junctions arrays with the direction of the applied dc current, both experimentally and numerically. We present computational simulations of current-voltage curves at finite temperatures for a single vortex in an array of $L\times L$ junctions ($Ha^2/?_0=f=1/L^2$), and experimental measurements in $100\times1000$ arrays under a low magnetic field corresponding to $f\approx0.02$. We find that the transverse voltage vanishes only in the directions of maximum symmetry of the square lattice: the [10] and [01] direction (parallel bias) and the [11] direction (diagonal bias). For orientations different than the symmetry directions, we find a finite transverse voltage which depends strongly on the angle φ of the current. We find that vortex motion is pinned in the [10] direction ($?=0$), meaning that the voltage response is insensitive to small changes in the orientation of the current near $?=0$. We call this phenomenon orientational pinning. This leads to a finite transverse critical current for a bias at $?=0$ and to a transverse voltage for a bias at $?\not=0$. On the other hand, for diagonal bias in the [11] direction the behavior is highly unstable against small variations of φ, leading to a rapid change from zero transverse voltage to a large transverse voltage within a few degrees. This last behavior is in good agreement with our measurements in arrays with a quasi-diagonal current drive.

Abstract: We have performed Bitter decoration and ac susceptibility measurements in single-crystal YBa2Cu3O7-delta with oriented twin boundaries. The twin boundaries (TB's) pin vortices over approximately 65% of the sample. The pinned areas are unevenly distributed and some relatively large TB-free regions are present. The Bitter decorations were performed in a 52 Oe de magnetic field rotated off the c axis so that the plane defined by the field direction and the c axis is perpendicular to the TB's. Several decorations were performed in the same sample. Additional dynamical information was obtained from ac susceptibility measurements. Results show that for small tilts the vortices remain locked to the c-axis direction, for angles greater than 12 degrees they form a staircase pattern, and in this case pinning by the twin boundaries remains effective up to 75 degrees. We observe vortex chains in twin-free-zones of the sample for tilted fields at 65 degrees and 40 degrees. Due to our particular experimental arrangement, in the twinned regions the interplay of the potentials giving rise to the chains and the pinning potential produces a structure with a disordered square symmetry. The data allow us to estimate the dominant energy of the vortex system for some inclinations of the applied magnetic field.

Abstract: Bitter decorations of the vortices in twinned single crystal YBCO have been obtained to study the disordered structure formed on successive cooldowns of the sample under the same conditions of field and temperature. Between succesive decorations, the iron dots could be removed completely, giving a surface clean enough for further decoration. It was found that successive realizations of the disordered vortex state were very similar at long range, and differed mostly on short scales, compared to the average vortex separation. We have quantified the correlation between successive structures, and double sided decorations have been also performed to compare with the extent of spatial correlation in the applied field direction. The coincidence of the position of the vortices in successive realizations of the structure, is unexpected, and indicates an unusual behavior for a glassy system. Our technique makes it possible to image the position of the vortices in detail and repeatedly, providing us with a model amorphous system in which to study the reproducibility of the disordered structure.